By use of ASTM C1202, this paper studied the influence of mineral admixtures on the chloride ions penetration resistance of the new-old concrete compound system. The results indicate that the performance of new-old concrete exert significant influence on the new-old concrete compound system. The addition of mineral admixtures improve the permeability properties of new-old concrete. Adding fly ash(FA) require a relatively longer time to get its beneficial effect. When 30% weight of cement is replaced by 10% FA and 20% ground blast furnace slag(GGBFS), the inclusion of 30% mineral admixtures significantly improve the chloride ions penetration resistance properties of the new-old concrete compound system at 28 days and 180 days.