In the process of engineering prospective design and constructing, it is necessary to avoid the adverse impact of geological phenomena, such as fault, karst and landslide. Therefore, it’s important to choose a favorable project address by scientific and effective detection with engineering geological conditions. The main exploration method for geological conditions is the geophysical exploration, including: high density electrical method, ground penetrating Radar, seismic exploration method and so on. The discrimination result with a single geological method changes much, and it is difficult to make an accurate analysis of the geological conditions. So we should composite a variety of exploration methods. In this paper, it expounds the fundamental, the working method, data explanations of the high density electrical method and ground penetrating Radar firstly. And then it takes exploration of candidate sites of an aluminum waste disposal plant for example, the geological conditions of candidate sites are analyzed under the two geophysical methods. The study results of engineering site option have a positive role in guiding the work.