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Correlation and Prediction of Vapor-Liquid Equilibrium for the Propylene Oxide-Ethanol-Water Ternary System

Journal Advanced Materials Research (Volumes 396 - 398)
Volume Advances in Chemical Engineering
Edited by Yanxuan Wen and Fuhou Lei
Pages 973-976
DOI 10.4028/www.scientific.net/AMR.396-398.973
Citation Cheng Xue Wang et al., 2011, Advanced Materials Research, 396-398, 973
Online since November, 2011
Authors Cheng Xue Wang, Rui Xia Jiang
Keywords Ethanol, NRTL Equation, Propylene Oxide, Vapor-Liquid Equilibrium (VLE), Water
Abstract

The vapor-liquid equilibrium (VLE) data for the binary systems ethanol-water (1), propylene oxide (PO)-ethanol (2), PO-water (3) and the ternary system PO-ethanol-water (4) were determined at 101.3kPa. The binary VLE data measured passed the thermodynamic consistency verification. The experimental VLE data of the binary systems were correlated with the nonrandom two-liquid (NRTL) models. The results show that the values of molar fraction of the ternary system (4) in vapor phase from the binary NRTL parameters agree well with the experimental data.

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