Synthesis of Fullerene-Acid Conjugates

Zhang, Jing; Yuan, Li; Zhang, Ya Dong

My Cart

Advanced Search

Paper Titles

Preparation and Properties of Nanocomposites Based on Poly(Lactic Acid) and Modified TiO₂, p.519
Preparation of Poly[4-Diacetoxyiodo] Styrene by Microwave Reactor, p.523
Synthesis and Characterization of Polystyrene-Graphite Nanocomposites via Surface Raft-Mediated Polymerization, p.527
Synthesis of FeC₂O₄-Graphene Composites and their Application in Removal Dyes, p.533
Synthesis of Fullerene-Acid Conjugates, p.538
Synthesis of Novel Core-Shell Structured Hydroxyapatite/Meso-Silica for Removal of Methylene Blue from Aqueous Solutions, p.543
Synthesis, Characterization of Electrospun Mesoporous ZnO/SnO₂ Composites Nanofibers and their Photocatalytic Property, p.548
Synthesis, Characterization, and Electrochemical Properties of Mn₃O₄/Cr₂O₃ Composite, p.555
The Effect of N Vacancy on GaN Doped by Fe, p.560

Home > Advanced Materials Research > Advanced Materials Research II > Synthesis of Fullerene-Acid Conjugates

Paper Title:

Synthesis of Fullerene-Acid Conjugates

Periodical	Advanced Materials Research (Volumes 463 - 464)
Main Theme	Advanced Materials Research II
Edited by	Wu Fan
Pages	538-542
DOI	10.4028/www.scientific.net/AMR.463-464.538
Citation	Jing Zhang et al., 2012, Advanced Materials Research, 463-464, 538
Online since	February, 2012
Authors	Jing Zhang, Li Yuan, Ya Dong Zhang
Keywords	Fullerene-Amino Acid Conjugate, Synthesis
Price	US$ 28,-

View full size

Abstract

N-substituted 3,4-fullero pyrrolidine was synthesized according to 1,3-Dipolar cycloaddition of the azomethine ylide. Aspartic acid and glutamic acid with protected α-amino and α-carboxyl groups were reacted with the activated hydroxyl group of N-substituted 3,4-fullero pyrrolidine, respectively. The products were deprotected, affording two novel fullerene α-amino acids, fullerene aspartic acid and fullerene glutamic acid. Their chemical structures were characterized by MALAI-TOF-MS, UV-Vis, FT-IR and 1HNMR. Both fullerene amino acids with a free amino group and a free carboxyl group would have unique property and potential use in medicine and biology. A novel method has been developed to synthesize fullerene conjugate. Their unique chemical structures make them very interesting for their potential use in medicine and biology.