Paper Title:
Assembling of 12-Tungstophosphoric Acid into Amino-Modified SBA-15 and its Catalytic Performance
| Periodical | Advanced Materials Research (Volume 465) |
|---|---|
| Main Theme | Advanced in Nanoscience and Technology |
| Edited by | Hailin Cong |
| Pages | 224-228 |
| DOI | 10.4028/www.scientific.net/AMR.465.224 |
| Citation | Hong Qi Guo et al., 2012, Advanced Materials Research, 465, 224 |
| Online since | February, 2012 |
| Authors | Hong Qi Guo, Gong Yan, Ming Qing Chen, Shi Rong Liu |
| Keywords | 12-Tungstophosphoric Acid, Amino Modification, Esterification, SBA-15, Supported Catalyst |
| Price | US$ 28,- |
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Abstract
12-tungstophosphoric acid was supported on amine-modified SBA-15 by impregnation. The structure and properties of the catalyst were characterized by FT-IR spectroscopy, X-ray diffraction, N2 adsorption-desorption, TEM,Raman spectra and NH3–TPD technology.the result confirmed the mesostructure for SBA-15 and the Keggin structure of the heteropolyanions was preserved. The tungstophosphoric acid can disperse in the pore of the support SBA-15/NH2, but the acidity of the catalyst reduced. The catalytic activities of the catalysts were evaluated for the esterification reaction of ethyl acetoacetate and ethylene glycol .and the catalysts supported on amine-modified SBA-15 show excellent reusability and selectivity.
