Paper Title:

Effect of Hydrothermally Prepared Graft Copolymer Addition on a Brittle Matrix: A Preliminary Study on Glass Fiber Reinforced PLA/LLDPE-g-MA Composite

Periodical Advanced Materials Research (Volume 530)
Main Theme Smart Technologies for Materials
Edited by Tianharry Chang
Pages 46-51
DOI 10.4028/www.scientific.net/AMR.530.46
Citation Anil Kunwar et al., 2012, Advanced Materials Research, 530, 46
Online since June, 2012
Authors Anil Kunwar, Roma Gurung, Seok Geun Park, Jae Kyoo Lim
Keywords Compatibility, Composite, Ductility Index, Fractography, FT-IR, Graft Copolymer, Green Chemistry Approach, Hydrothermal, Matrix Ductility, Scanning Electron Microscope (SEM)
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Abstract

Green chemistry approach (hydrothermal process) is utilized for grafting maleic anhydride (MA) into linear low density polyethylene (LLDPE), thereby enhancing the compatiblility of the latter in its blend with polylactic acid (PLA). The grafting of MA into LLDPE is confirmed by Fourier Transform-Infrared Spectroscopy (FT-IR) analysis. LLDPE-g-MA content in PLA matrix is varied as 4% wt., 8% wt. and 12% wt. when preparing glass fiber reinforced PLA/LLDPE-g-MA thermoplastic composite via hot pressing. Single Edge Notch Bend (SENB) specimens have been prepared from the composites and three point bend test was performed.The load-displacement plot of the test results indicates that the ductility index (DI) increased for the samples with increased LLDPE-g-MA content. The observation of the fractured surface of specimens in Scanning Electron Microscope (SEM) suggests that the improved DI value is because of the increased matrix ductility owing to the plasticizing effect of the LLDPE-g-MAH inclusion.