A noncrystalline SrTiO3 (STO) thin film was grown on Pt/Ti/SiO2/Si substrates by pulsed laser deposition. The Pt thin film was deposited on STO film as top electrode, forming a symmetric structure (Pt/STO/Pt) to exclude the influence of the electrical difference in STO-electrode interfaces. It was found that a stable bipolar resistive switching was obtained in this structure. In a current sweep, an obvious S type negative differential conductance (NDC) phenomenon was found in both polarities. And in a voltage sweep, no NDC was observed due to the current control mechanism of S type NDC effect. The possible mechanism of this effect is discussed preliminarily.