Paper Title:
Synthesis, Structure and Electrochemical Behavior of a Supramolecular Compound
  Abstract

A supramolecular compound, Co(C5H4NCOO)2(H2O)2∙2H2O was hydrothermally synthesized and characterized by elemental analysis, infrared spectra, UV-vis spectra. Elemental analysis result shows that the mass percent of C is 38.36%; H, 4.32% and N, 7.50%. Infrared spectra show that the main absorption peak is near 3396 cm-1, which is attributed to the O-H stretching vibration absorption. Also there are some absorption peaks at 1599, 1551, 1420, 1384 cm-1, which are attributed to the pyridine vibration absorption. UV spectrum for the compound shows strong absorption peaks at 203 and 259 nm, which are similar to isoniazid. X-ray diffraction data indicate that the compound is monoclinic, P21 / c space group. The cyclic voltammograms indicate that the compound decreases the rate of oxygen reduction reaction (ORR) and induces the ORR more difficult in aqueous solutions. The electrochemical behavior suggests that the compound possesses the potential application for corrosion in aqueous environment.

  Info
Periodical
Advanced Materials Research (Volumes 79-82)
Edited by
Yansheng Yin and Xin Wang
Pages
1475-1478
DOI
10.4028/www.scientific.net/AMR.79-82.1475
Citation
Z. F. Lin, S. F. Zhang, D. Zhang, "Synthesis, Structure and Electrochemical Behavior of a Supramolecular Compound ", Advanced Materials Research, Vols. 79-82, pp. 1475-1478, 2009
Online since
August 2009
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Jian Yang, Tai Qiu, Chun Ying Shen
Abstract:An organic precursor was synthesized with C3N6H6 and H3BO3 as raw materials in aqueous solution. A novel amorphous BCN compound was obtained...
1080
Authors: Yan Bing Zhang, Ting Zhang, Xian Li Yang, Wen Tao Zhang, Xiao Jing Wang
Abstract:A new charge-transfer coordination compound [(C5S5H3CH2O)4Ni](FeCp2)0.84 was synthesized in this work. The molecular formula of the...
85
Authors: Yan Xia Song, Chong Chen Wang, Yuan Lan Wang
Abstract:Two two-dimensional and three-dimensional coordination-polymer, [Ni(2,2′,5,5′-bpdc) (H2O)]•H2O (1) and[Ni(2,2′,6,6′-bpdc)2]•4H2O (2) were...
144
Authors: Fei Fei Liang, Yan Ming Hao, Yan Zhao Wu
Metal Alloy Materials
Abstract:The thermal expansion and the Curie temperature of Tm2Fe15SiCr compound have been investigated by means of x-ray...
764
Authors: You Ming Shen, Si Meng Yang, Li Chao Xi, Wen Yan Cao, Li Li Zhou, Yao Yang, Shao Dong Feng, Xue Fen Peng, Xiang Yang Zhang, Chun Xiang Zhang, Jun Ling Jin, Qing Yun Zhen
Chapter 12: Measurement Technology, Instruments and Sensors, Monitoring, Detection Technologies and Methodologies
Abstract:A water-soluble fluorescent probe was described for detecting hydrogen peroxide with the naphthalimide derived as fluorophore and boronate...
978