Paper Title:
A Novel Poly(Ferrocenyl-Schiff Base) and its Charge Transfer Complex with Iodine
  Abstract

A ferrocenyl Schiff base monomer was synthesized through the condensation of ferrocenecarboxaldehyde and phenylenediamine under neutral conditions, and then been used to produce copolymer materials with terephthaloyl chloride monomer by the Friedel-Crafts method. The model compound and copolymer of a novel poly(ferrocene-Schiff base) and their charge transfer complex with iodine was successful obtained, their structures been characterized by 1H-NMR spectra, infrared spectra, and ultraviolet spectra. In addition, the effects of iodine doping degree on its structure was studied, the electrical measurement results showed its conductivity can be increased several orders of magnitude after doping with iodine, the maximum conductivity at room temperature is 3.17×10-4 S•cm-1.

  Info
Periodical
Advanced Materials Research (Volumes 97-101)
Edited by
Zhengyi Jiang and Chunliang Zhang
Pages
634-637
DOI
10.4028/www.scientific.net/AMR.97-101.634
Citation
G. X. Xiong, H. Q. Huang, C. Yang, "A Novel Poly(Ferrocenyl-Schiff Base) and its Charge Transfer Complex with Iodine", Advanced Materials Research, Vols. 97-101, pp. 634-637, 2010
Online since
March 2010
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Hui Huang, Jin Quan Xu, Zhong Cheng Guo
Abstract:Conductive polyaniline (PANI) was synthesized by the oxidation of aniline with complex oxidant composed of ammonium persulfate ((NH4)2S2O8)...
300
Authors: Kwan Ho Park, Il Ho Kim
Abstract:Co4-xFexSb12-ySny skutterudites were synthesized by mechanical alloying and hot pressing, and...
65
Authors: Afarin Bahrami, Z.A. Talib, W. Mahmood Mat Yunus, Kasra Behzad, Nayereh Soltani
Abstract:This study describes the preparation of polypyrrole multiwall carbon nanotube (PPy/MWNT) composites by in situ chemical oxidative...
50
Authors: Xiu Qin Wang, Jian Ning Ding, Ning Yi Yuan, Shu Bo Wang
Chapter 5: Nano Material Research/Nanotube/Nanowire Devices
Abstract:Boron-doped nanocrystalline silicon thin films(p-nc-Si:H) were deposited on glass substrates by plasma enhanced chemical vapour deposition...
386
Authors: Zheng Chen, Rui Qi Li, Qing Guo
Chapter 12: Functional Materials
Abstract:Conductive polyaniline(PANI) was synthesized by chemical oxidative copolymerization , using dodecylbenzene sulfonic acid (DBSA)as doping...
1166