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Catalytic and Electrical Properties of Electrochemical NOx Reduction System

Journal Advances in Science and Technology (Volume 45)
Volume 11th International Ceramics Congress
Edited by P. VINCENZINI
Pages 2039-2042
DOI 10.4028/www.scientific.net/AST.45.2039
Citation Toshiaki Yamaguchi et al., 2006, Advances in Science and Technology, 45, 2039
Online since October, 2006
Authors Toshiaki Yamaguchi, Yuko Kato, Koichi Kikuta, Toshio Suzuki, Yoshinobu Fujishiro, Masanobu Awano, Shin Ichi Hirano
Keywords Ceria Electrolyte, Electrochemical System, NOx Reduction
Abstract

The catalytic and electrical properties of an electrochemical NOx reduction system were investigated. A power above 3.5W/cm2 reduced more than 60% of NOx to N2 over the (La,Sr)CoO3-α/Ce0.9Gd0.1O1.95/Pt laminated system in a temperature range of 450°C to 650°C. O2- transportation removed the oxygen around the cathode layer through the Ce0.9Gd0.1O1.95 electrolyte layer, then NO was able to decompose to N2 at the cathode. This ceria-based system exhibited stable NOx reduction with respect to electrical power, regardless of operating temperature.

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