Periodic Pattern Formation in Metal-Ceramic Reactions |
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| Journal | Advances in Science and Technology (Volume 46) |
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| Volume | Mass and Charge Transport in Inorganic Materials III |
| Edited by | P. VINCENZINI and V. BUSCAGLIA |
| Pages | 136-145 |
| DOI | 10.4028/www.scientific.net/AST.46.136 |
| Citation | A.A. Kodentsov et al., 2006, Advances in Science and Technology, 46, 136 |
| Online since | October, 2006 |
| Authors | A.A. Kodentsov, F.J.J. van Loo |
| Keywords | Kirkendall Effect, Metal-Ceramic Reaction, Periodic Pattern |
| Abstract | Formation of diffusion zone morphologies periodic in time and space during metalceramic reactions is considered as a manifestation of the Kirkendall effect. In a diffusion-controlled interaction, the Kirkendall marker plane can bifurcate, which is attributed to diverging vacancies fluxes in the reaction zone. When the Kirkendall plane is present in a phase layer, it attracts in situproduced inclusions of “secondary-formed phase”, which, in turn, can result in a highly patterned microstructure. |
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