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Extraction of Diffusion Correlation Information from Tracer, Interdiffusion and Ionic Conductivity Data

Journal Advances in Science and Technology (Volume 46)
Volume Mass and Charge Transport in Inorganic Materials III
Edited by P. VINCENZINI and V. BUSCAGLIA
Pages 54-62
DOI 10.4028/www.scientific.net/AST.46.54
Citation Irina V. Belova et al., 2006, Advances in Science and Technology, 46, 54
Online since October, 2006
Authors Irina V. Belova, Graeme E. Murch
Keywords Diffusion, Interdiffusion, Ionic Conductivity, Tracer Diffusion
Abstract

In this paper, the current understanding about the relationships between tracer diffusion coefficients, interdiffusion coefficients and d.c. ionic conductivities in metallic alloy and ionic systems is reviewed with emphasis on recent progress. Quasione component systems are analyzed in terms of the Haven Ratio (and tracer and collective correlation factors). Two and three component alloy systems are analyzed in terms of the Darken-Manning equation and vacancy-wind factors (and tracer and collective correlation factors). Ionic systems with two mobile components are analyzed in terms of a corrected Nernst-Planck Equation.

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