Paper Title:
New Electroconducting Radical Cation Salts Based on BEDT-TTF with 8,8’-Dibromo Cobalt Bis(Dicarbollide) Anion
  Abstract

New molecular conductors on the base of 8,8’-dibromo cobalt bis(dicarbollide) anion, (BEDT-TTF)2[8,8’-Br2-3,3’-Co(1,2-C2B9H10)2] (1), and (BEDT-TTF)[8,8’-Br2-3,3’-Co(1,2-C2B9H10)2] (2) were synthesized and their crystal structures and electrical conductivities were determined. Both radical cation salts prepared were found to be semiconductors. The introduction of two bromine atoms in the cobalt bis(dicarbollide) anion produces a strong effect on crystal structure and electrical conductivity of the prepared materials.

  Info
Periodical
Edited by
Pietro VINCENZINI and Giuseppe D'ARRIGO
Pages
331-336
DOI
10.4028/www.scientific.net/AST.54.331
Citation
O. Kazheva, G. Alexandrov, A. Kravchenko, V. Starodub, I. Lobanova, I. Sivaev, V. Bregadze, L. Titov, O. Dyachenko, "New Electroconducting Radical Cation Salts Based on BEDT-TTF with 8,8’-Dibromo Cobalt Bis(Dicarbollide) Anion", Advances in Science and Technology, Vol. 54, pp. 331-336, 2008
Online since
September 2008
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