Paper Title:

Use of Sodium Silicate Gel as Precursor of Binder for Cold Consolidated Materials

Periodical Advances in Science and Technology (Volume 69)
Main Theme 12th INTERNATIONAL CERAMICS CONGRESS PART H
Edited by Pietro VINCENZINI and Cristina LEONELLI
Pages 57-62
DOI 10.4028/www.scientific.net/AST.69.57
Citation Monique Tohoué Tognonvi et al., 2010, Advances in Science and Technology, 69, 57
Online since October, 2010
Authors Monique Tohoué Tognonvi, Séka Simplice Kouassi, Toyotaka Maeda, Julien Soro, Sylvie Rossignol, Jean Pierre Bonnet
Keywords Concentrated Sodium Silicate Solution, Consolidated Material, Dissolution-Precipitation, Shrinkage, Ternary Diagram
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Abstract

Consolidation of cements and geopolymers can be explained by the formation of alkali silicate or alumino-silicate gels formed in situ during materials setting. To control such a system, a study concerning the use of sodium silicate gel as binder was initiated to manufacture consolidated materials with different size distribution of silica. The gels used as precursor of binder were synthesised by acidifying with hydrochloric acid, a concentrated sodium silicate. Consolidated materials were obtained by mixing the previous solution before gelation with granular materials (fine silica powder and sands). The existence domain of consolidated materials depends on the size distribution of sand. Consolidation of material is strong when the amount of silica is high. This result suggests a dissolution / precipitation reaction between gel and silica. Therefore, consolidation could be explained by the dissolution of small particles of silica and their precipitation into the grain boundary of sand. Mechanical properties are closed to those of cement materials.