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Effect of Solidification Rate and Composition on Segregation in Al-Li-Cu-Zr Alloys

Journal Defect and Diffusion Forum (Volumes 258 - 260)
Volume Diffusion in Solids and Liquids
Edited by Andreas Öchsner and José Grácio
Pages 15-19
DOI 10.4028/www.scientific.net/DDF.258-260.15
Citation Shahram Ahmadi et al., 2006, Defect and Diffusion Forum, 258-260, 15
Online since October, 2006
Authors Shahram Ahmadi, Ali Shokuhfar, S.M.M. Hadavi, Arash Rezaei, H. Azimi
Keywords Al-Li-Cu-Zr, Differential Thermal Analysis (DTA), Segregation, Solidification
Abstract

In the present study, solidification and segregation of Al-Li-Cu-Zr alloys have been investigated. Results show that shape of ingots and amount of lithium can change solidification essence. Increasing solidification rate, not only eliminates grain-refining effect of zirconium but also causes coarse segregation of copper in grain boundaries (negative segregation). Increasing amount of lithium in Al-Cu-Li-Zr alloys can change the solubility of other alloying elements (Cu, Zr) and increase solidification range and microsegregation of copper in structure.

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