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Diffusion of Carbon and Manganese in Fe-C-Mn

Journal Defect and Diffusion Forum (Volume 263)
Volume Diffusion and Thermodynamics of Materials
Edited by J. Čermák and I. Stloukal
Pages 153-158
DOI 10.4028/www.scientific.net/DDF.263.153
Citation Lubomir Král et al., 2007, Defect and Diffusion Forum, 263, 153
Online since March, 2007
Authors Lubomir Král, B. Million, Jiří Čermák
Keywords Diffusion, Diffusion Interaction Coefficients, Interdiffusion, Steel, Wagner's Coefficients
Abstract

In this paper, the results of measurements of chemical diffusion of C in weldments of Fe- C-Mn alloys with content of 0-15 % Mn, are reported. Alloys were cast in induction furnace under protective Ar atmosphere. They were hot-forged to rods of diameter 15 mm, machined down to diameter 12 mm, and cut into pieces of 4 mm thickness. These cylindrical samples were metallographically polished. Diffusion couples, welded by electrical impulse, were sealed together with Ti-chips, into evacuated silica ampoules. After that, they were annealed at 1073-1373 K for 96-1.5 hours, respectively. Measurement of C redistribution was done in a normal direction to welding interface using electron-scanning microscope Philips SEM-505WDS equipped with Microspec WDX-2A. Diffusion coefficients of C were obtained and the relations between manganese and carbon were found.

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