Interdiffusion Behavior in γ-Phase U-Mo Alloy versus Al-6061 Alloy Couples Fabricated by Friction Stir Welding |
| Journal |
Defect and Diffusion Forum (Volume 266) |
| Volume |
Diffusion in Advanced Materials and Processing |
| Edited by |
Y.H. Sohn, C. Campbell, D. Lewis and A. Lupulescu |
| Pages |
131-148 |
| DOI |
10.4028/www.scientific.net/DDF.266.131 |
| Online since |
September, 2007 |
| Authors |
Dennis D. Keiser
|
| Keywords |
Aluminum, Diffusion Couples, Interdiffusion, Nuclear, Uranium |
| Abstract |
To better understand interactions between fuel and cladding in research reactor fuels,
diffusion couples between γ-phase U-7 wt% Mo and U-10 wt% Mo alloy fuels and a Si-bearing, Al
alloy were fabricated using a friction stir welding technique. The advantage of such a fabrication
technique is that it can potentially reduce the amount of aluminum-oxide that might be present at the
diffusion couple interface. The presence of oxides at the interface can affect the interdiffusion process.
These couples were annealed and characterized using a scanning electron microscope equipped with
energy-dispersive and wavelength-dispersive spectrometers. Images were taken of the developed
diffusion structures; x-ray maps were generated to identify partitioning behavior of the various
components; and, point-to-point analysis was employed to generate composition profiles and to
determine phase compositions. To try and determine how the presence of Si in an Al alloy affects the
interdiffusion behavior of fuel and cladding components in research reactor nuclear fuels, the results
from this study were compared to those from earlier diffusion studies using U-Mo alloys and Al. The
formed diffusion zones in some samples annealed for 30 minutes are comprised of Si-rich aluminide
phases that appear to be (U,Mo)0.9(Al,Si)4 and (U,Mo)(Si,Al)2, based on composition. The diffusion
rates observed and the types of phases that form can be correlated to the stability of the γ-U phase,
which is a metastable phase. For a sample annealed for a much longer time, large diffusion structures
formed and no Si-rich phases were observed. |
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