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Effect of Synthesis Temperature on the Morphology of ZnO Nanoparticles Obtained via a Novel Chemical Route

Journal Defect and Diffusion Forum (Volumes 273 - 276)
Volume Diffusion in Solids and Liquids III
Edited by Andreas Öchsner and Graeme E. Murch
Pages 192-197
DOI 10.4028/www.scientific.net/DDF.273-276.192
Citation Javad Samei et al., 2008, Defect and Diffusion Forum, 273-276, 192
Online since February, 2008
Authors Javad Samei, Ali Shokuhfar, A. Esmaielzadeh Kandjani, Mohammad Reza Vaezi
Keywords Chemical Bath Deposition (CBD), Morphology, Synthesis Temperatures, ZnO Nanoparticle
Abstract

ZnO as a semiconductor is used in many applications such as gas sensor devices, laser and optoelectronic devices, photocatalysts, solar cells, and varistors. The applications and properties of ZnO nanoparticles highly depend on the size and morphology of these particles. In this research ZnO nanoparticles were prepared via chemical bath deposition at various temperatures in order to see the effects of synthesis temperature and also 2- methoxyethanol (2-ME) as a novel solvent on the morphology of obtained nanoparticles. For synthesizing of ZnO nanostructured materials, 2-ME has been highly used in sol-gel process but it is the first time that it is used in the chemical bath deposition process. For this purpose 1 M solutions of zinc acetate dehydrate in 2-ME were prepared and added to the solution of NaOH in the same solvent dropwisely. Monoethanolamine (MEA) was used as surfactant. The synthesis temperatures were 30°C, 60°C and 90°C. After filtering and drying, morphologies of obtained nanoparticles were characterized and compared.

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