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Oxygen Isotope Exchange between Gaseous Phase Enriched with 18O Isotope and Nanocrystal Oxides LaMnO3+δ Obtained by Severe Plastic Deformation

Journal Defect and Diffusion Forum (Volumes 273 - 276)
Volume Diffusion in Solids and Liquids III
Edited by Andreas Öchsner and Graeme E. Murch
Pages 233-238
DOI 10.4028/www.scientific.net/DDF.273-276.233
Citation B.A. Gizhevskii et al., 2008, Defect and Diffusion Forum, 273-276, 233
Online since February, 2008
Authors B.A. Gizhevskii, A.Ya. Fishman, E.A. Kozlov, T.E. Kurennykh, S.A. Petrova, I.Sh. Trakhtenberg, E.V. Vykhodets, V.B. Vykhodets, R.G. Zakharov
Keywords Diffusion, Isotope, Nanoparticle, Nuclear Microanalysis, Oxide, Oxygen
Abstract

The kinetics of the isotope exchange between gaseous oxygen enriched with the 18O isotope and two LaMnO3+δ oxide samples – a nanopowder and a bulk nanocrystal – has been studied. The 18O isotope concentration has been measured by the acceleration nuclear microanalysis method. The coefficients of the volume and the nanograin boundary self-diffusion of oxygen have been evaluated at 500 °C. They are equal to 3.5·10 −20 and 1.5·10 −13 cm2/s, respectively.

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