Paper Title:
Influence of Elements Oxides Microadditives with Major Cationic Radius on Properties of Silicate Bundle
  Abstract

For the agglomerates of the Kachkanar deposit iron ore the role of elements with ionic radius larger than for magnesium and calcium in the formation of the strength characteristics and parameters of the viscous-plastic state of iron-ore materials is shown. The strength characteristics of high-quality sinters are largely defined by the low stressed state of a silicate bundle which is formed in the cake cooling-down period. The diffusion processes at the glasses recrystallization at the cakes refrigeration can be reduced by injection of the elements impeding these processes and having low -strength cation-oxygen connections, that, apparently, should ¬ hinder in formation of the crystals with their participation. From these positions the stabilizing additions are the cations of heavy elements having major radius and remote from the valence electrons¬. It according to the theory of the stressed state of the oxide ¬ systems is accompanied by the grain refinement, decrease of the microstresses ¬ and fissurings of the glass matrix and therefore the defectiveness of cake structure. On the basis of the mathematical model leaning on the results of the dilatometric explorations the positive influence of the microadditives of the barium oxide on increase of temperature of beginning and narrowing of the softening range of sinters is revealed.

  Info
Periodical
Defect and Diffusion Forum (Volumes 297-301)
Edited by
Andreas Öchsner, Graeme E. Murch, Ali Shokuhfar and João M.P.Q. Delgado
Pages
1295-1300
DOI
10.4028/www.scientific.net/DDF.297-301.1295
Citation
A.N. Dmitriev, V.P. Perepechaev, Y.A. Chesnokov, "Influence of Elements Oxides Microadditives with Major Cationic Radius on Properties of Silicate Bundle ", Defect and Diffusion Forum, Vols. 297-301, pp. 1295-1300, 2010
Online since
April 2010
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: M. Grofmeier, F.V. Natrup, Hartmut Bracht
Abstract:Diffusion of alkaline-earth ions in mixed cation glasses of the composition xA2O•(3-x)MO•4SiO2 (x = 0.0, 0.1, 0.3, 0.4 and 1.0; A = Na, K; M...
615