Studies of the EPR Parameters and Local Structure for the Cu2+ Center in Lanthanum Magnesium Nitrate

Xu, Pei; Kuang, Min Quan; Zhang, Shan Xiang

Get full access here Site/IP Subscriptions Log in

My Cart

Advanced Search

Paper Titles

Formulation of Impurity-Vacancy Pair Formation Energy in Fast Diffusion, p.49
Theoretical Study of the Local Distortion for Ni⁺ in Magnesium Oxide, p.55
A Study of the Physical Properties of Te₁₅(Se_100-xBi_x)₈₅ Glassy Alloys, p.61
Non-Gaussian Local Density Diffusion (LDD-) Model for Boron Diffusion in Si- and Si_xGe_1-x Ultra-Shallow Junction Post-Implant and Advanced Rapid-Thermal-Anneals, p.71
Studies of the EPR Parameters and Local Structure for the Cu²⁺ Center in Lanthanum Magnesium Nitrate, p.85
Synthesis and Characterization of Zinc Phosphates in Aqueous and Non-Aqueous Media with (2-Hydroxyethyl) Trimethyl Ammonium Hydroxide as Template, p.89
Simulation-Based Apparent Surface Free-Energy Analysis for Hydrophobic and Superhydrophobic Surfaces, p.95
Study of the Dielectric, Magnetic and Resistive Properties of Various Substances, p.105
Improvement of the Modified Dry-Cup Method for Determination of the Diffusion Coefficients of Gaseous Pollutants in Building Materials, p.109

Home > Defect and Diffusion Forum > Defects and Diffusion in Metals XII > Studies of the EPR Parameters and Local Structure...

Paper Title:

Studies of the EPR Parameters and Local Structure for the Cu²⁺ Center in Lanthanum Magnesium Nitrate

Periodical	Defect and Diffusion Forum (Volumes 305 - 306)
Main Theme	Defects and Diffusion in Metals XII
Edited by	David J. Fisher
Pages	85-88
DOI	10.4028/www.scientific.net/DDF.305-306.85
Citation	Min Quan Kuang et al., 2010, Defect and Diffusion Forum, 305-306, 85
Online since	October, 2010
Authors	Min Quan Kuang, Shan Xiang Zhang, Pei Xu
Keywords	Cu²⁺, Defect Structures, Electron Paramagnetic Resonance (EPR), Lanthanum Magnesium Nitrate
Price	US$ 28,-

View full size

Abstract

The electron paramagnetic resonance parameters (g-factors and the hyperfine structure constants) for the Cu2+ center in lanthanum magnesium nitrate (LMN) are theoretically studied from the conventional perturbation formulas of these parameters for a 3d9 ion in tetragonally elongated octahedra. The studied complex is found to exhibit the slight tetragonal elongation (characterized by the relative elongation ratio ρ  4%) due to the Jahn-Teller effect, which may entirely conceal the original trigonal distortion of the host Mg2+ site in LMN. The conventional formulas containing only the metal orbital and spin-orbit coupling contributions are proved to be valid for the Cu2+ center in view of the weak covalency and ligand spin-orbit coupling interactions. This defect is also compared with the similar Cu2+ center of the Jahn-Teller nature on the octahedral interstitial site in the CdSe nanocrystals.