Multivariate analysis was conducted to analyze the relationship between air pollutants and meteorological variables measured in Seoul from January 1 to December 31, 1999. The first principal component showed the contrast effect between O3 and the other pollutants. The second principal component showed the contrast effect between CO, SO2, NO2, and O3, PM10, TSP. Based on the cluster analysis, three clusters represented different air pollution levels, seasonal characteristics of air pollutants, and meteorological conditions. Discriminant analysis with Air Environment Index (AEI) was carried out to develop an air pollution index function.