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Effects of Lanthanum Modification on the Structure and Electrical Properties of PZN-PZT Ceramics

Journal Key Engineering Materials (Volumes 280 - 283)
Volume High-Performance Ceramics III
Edited by Wei Pan, Jianghong Gong, Chang-Chun Ge and Jing-Feng Li
Pages 227-230
DOI 10.4028/www.scientific.net/KEM.280-283.227
Citation X. Zeng et al., 2007, Key Engineering Materials, 280-283, 227
Online since February, 2007
Authors X. Zeng, Ai Li Ding, X.S. Zheng, Yong Zhang, Ping Sun Qiu
Keywords Electrical Properties, Lanthanum Doped, Microstructure, PZN-PZT
Abstract

La-modified PZN-PZT compositions with representative formula Pb1-0.7xLa0.7x(Zn1/3Nb2/3)0.3- (Zr0.55Ti0.45)0.7(1-x/4)O3 were prepared by the columbite precursor method. La content, x, was varied from 0 to 8mol%. Effects of La doping on microstructure, dielectric and piezoelectric properties were investigated. The results showed that in present system La doping promotes the formation of pyrochlore phase and the phase shifted from rhombohedral to tetragonal structure with increasing La content. It was also found that La doping makes dielectric permittivity maximum decrease and the degree of diffuse phase transition enhance. Appropriate amount of La doping could improve the piezoelectric properties.

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