Paper Title:
The Influence and Mechanism of the Electrical Conductivity of (Ca,Sr)Bi4Ti4O15 Piezoelectric Ceramics by Doping of CeO2
  Abstract

In this paper, the bismuth-layered structure piezoelectric ceramics (Ca,Sr)Bi4Ti4O15 doped with CeO2 are prepared by the solid state reaction method. The crystal structure of the ceramics is determined by X-ray diffraction and the single orthorhombic structure phase is found. However, the doping of CeO2 increase the lattice parameters a, b, c. As a result, the ions of Ce enter into the lattice of the bismuth-layered structure and occupy A sites in the perovskite layer of bismuthlayered structure lattice. The temperature dependence of the conductivity shows that the resistivity increases by doping of CeO2 and reaches its maximum when the doping content is 0.4mol%. The mechanism of the CeO2 doping is also analyzed. By the investigation of XPS, the Ce ions have two types of valences: Ce3+ and Ce4+. The existence of Ce ions strengthened the weak Bi-O bonding and decreased the oxygen vacancies in the lattice, so the ceramics have lower conductivity.

  Info
Periodical
Key Engineering Materials (Volumes 280-283)
Edited by
Wei Pan, Jianghong Gong, Chang-Chun Ge and Jing-Feng Li
Pages
263-266
DOI
10.4028/www.scientific.net/KEM.280-283.263
Citation
L. Y. Zheng, G. R. Li, W. Z. Zhang, Q. R. Yin, "The Influence and Mechanism of the Electrical Conductivity of (Ca,Sr)Bi4Ti4O15 Piezoelectric Ceramics by Doping of CeO2", Key Engineering Materials, Vols. 280-283, pp. 263-266, 2005
Online since
February 2007
Export
Price
$32.00
Share

In order to see related information, you need to Login.

In order to see related information, you need to Login.

Authors: Kenichi Kakimoto, Izumi Masuda, Hitoshi Ohsato
7
Authors: Jing Pei, Zhen Xing Yue, Fei Zhao, Zhi Lun Gui, Long Tu Li
Abstract:The nano-sized Ba(Zr0.2Ti0.8)O3 powder was prepared by citrate sol-gel method. The crystal structure and the particle size of the powder...
76
Authors: Qiang Chen, De Jun Lan, Yi Chen, Du Min Lin, Xi Yue, Ding Quan Xiao, Jian Guo Zhu
Abstract:Lead-free piezoelectric ceramics lithium sodium potassium niobate (LixNayK1-x-y)NbO3 (LNKN100x/100y) have been synthesized by a conventional...
199
Authors: Xin You Huang, Chun Hua Gao, Zhi Gang Chen
2663
Authors: Rong Xia Huang, Yu Zhen Zhao, Yong Jie Zhao, Rong Zheng Liu, He Ping Zhou
Abstract:Lead-free K0.5Na0.5NbO3-xwt% (0.4ZnO-0.6B2O3) ceramics were synthesized by...
315