CCD camera is used in the liquid signature analyzer system to capture images of the liquid drop of the tested sample. The digital image processing work is presented. CCD camera records the variation of the liquid drop during growth. The outline information of the drop is available through image processing. The instantaneous volume of the liquid drop can be gained through mathematical calculation. With the use of CCD camera, the information of the tested sample we can get during the measurement is enhanced. The function of the liquid signature analyzer is enriched and the discrimination ability of this technology is improved.