Paper Title:

Chemical Solution Deposition of PZT/Oxide Electrode Thin Film Capacitors with Preferred Orientation on Si Substrate

Periodical Key Engineering Materials (Volume 301)
Main Theme Electroceramics in Japan VIII
Edited by Masaru Miyayama, Tadashi Takenaka, Masasuke Takata and Kazuo Shinozaki
Pages 269-272
DOI 10.4028/www.scientific.net/KEM.301.269
Citation Hisao Suzuki et al., 2006, Key Engineering Materials, 301, 269
Online since January, 2006
Authors Hisao Suzuki, Yuki Miwa, Tomoya Ohno, Masayuki Fujimoto
Keywords CSD, Electrical Property, Orientation Control, Perovskite-Type Oxide Electrode Thin Films, PZT/Oxide Electrode Thin Film Capacitors
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Abstract

This paper describes the deposition of PZT/oxide electrode thin film capacitors on Si(100) substrate with a CSD (Chemical Solution Deposition). Highly (100)&(001)-oriented SRO/LNO electrode films with a perovskite structure were obtained by the annealing at 700 °C from a precursor solution of Sr and RuCl3·2H2O for SRO and from a precursor solution of La(NO3)3 and Ni(CH3COO)2 for LNO. In addition, highly (100)&(001)-oriented PZT/oxide electrode capacitor were deposited on SRO/LNO/Si substrate by annealing at 650 °C, showing a good ferroelectricity of Pr=22μC/cm2 and Ec=55 kV/cm. In addition, the resultant PZT/oxide electrode thin film capacitors exhibited no fatigue up to 108 switching cycles.