Paper Title:

Development of Lead-Free Piezoelectric Materials Using Domain Wall Engineering

Periodical Key Engineering Materials (Volume 320)
Main Theme Electroceramics in Japan IX
Edited by Keiichi Katayama, Kazumi Kato, Tadashi Takenaka, Masasuke Takata and Kazuo Shinozaki
Pages 151-154
DOI 10.4028/www.scientific.net/KEM.320.151
Citation Satoshi Wada et al., 2006, Key Engineering Materials, 320, 151
Online since September, 2006
Authors Satoshi Wada, Koichi Yako, Tomomitsu Muraishi, Hirofumi Kakemoto, Takaaki Tsurumi
Keywords Barium Titanate, Domain Wall, Domain Wall Engineering, Engineered Domain Configuration, Lead-Free Piezoelectric, Piezoelectric Properties, Single Crystal
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Abstract

For the [111] oriented barium titanate (BaTiO3) single crystals, the patterning electrode was applied to induce the finer engineered domain configurations with domain size of 3 2m. The poling treatment was performed at 134 ˚C under electric fields below 6 kV/cm to inhibit the burning of the patterning electrode with photoresist. As the results, the gradient domain sizes from 3 to 8-9 2m were induced into the 31 resonator. The d31 was measured at -243.2 pC/N, and this value was almost 70 % of the expected d31 of –337.7 pC/N for the resonator with domain size of 3 2m. This difference was originated from lower applied electric field below 6 kV/cm. However, this study was revealed that the patterning electrode was very powerful tool to induce much finer domain sizes below 5 2m.