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Studies on Cadmium Uptake by Hydroxyapatite

Journal Key Engineering Materials (Volumes 330 - 332)
Volume Bioceramics 19
Edited by Xingdong Zhang, Xudong Li, Hongsong Fan, Xuanyong Liu
Pages 123-126
DOI 10.4028/www.scientific.net/KEM.330-332.123
Citation Nilce C.C. da Rocha et al., 2007, Key Engineering Materials, 330-332, 123
Online since February, 2007
Authors Nilce C.C. da Rocha, Elena Mavropoulos, Marcelo Henrique Prado da Silva, R. C. de Campos, Antonella M. Rossi
Keywords Cadmium (Cd), Complexation, Ion-Exchange, Mechanism
Abstract

Cadmium uptake by hydroxyapatite from aqueous solution was studied in time intervals between 2 minutes and 96 hours, using different Cd2+ concentrations (21 to 768 mg L-1). The solution pH after Cd2+ uptake was assessed. Dissolution experiments at fixed pH were performed in order to evaluate the ion exchange process. Cd2+sorption by hydroxyapatite is fast and it happens simultaneously by different mechanisms. Ion exchange is the main mechanism, where mechanism Cd2+ present in aqueous solution replaces Ca2+ from hydroxyapatite structure.

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