Paper Title:

Surface Defects Repairing by Polymer Coating with Low Fraction of Nano-Reinforcements

Periodical Key Engineering Materials (Volumes 334 - 335)
Main Theme Advances in Composite Materials and Structures
Edited by J.K. Kim, D.Z. Wo, L.M. Zhou, H.T. Huang, K.T. Lau and M. Wang
Pages 757-760
DOI 10.4028/www.scientific.net/KEM.334-335.757
Citation Shang Lin Gao et al., 2007, Key Engineering Materials, 334-335, 757
Online since March, 2007
Authors Shang Lin Gao, Edith Mäder, Rosemarie Plonka
Keywords Nanostructure, Coating, Corrosion, Glass Fiber, Heal, Surface Defects
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Abstract

Surface defects cause the measured tensile strength of glass and other brittle materials significantly lower than their theoretical values. Here, we describe an on-line process to ‘heal’ surface flaws and functionalise surface properties. A nanometer-scale hybrid coating layer based on styrene-butadiene copolymer with mutiwalled carbon nanotubes (MWCNTs) and/or nanoclays, as mechanical enhancement and environmental barrier layer, is applied to alkali-resistant glass fibres (ARG). The nanostructured and functionalised traditional glass fibres with low fraction of nanotubes or nanoclay (1 wt% in sizing) show significant improvement in both mechanical properties and environmental corrosion resistance. We introduce a healing efficiency factor and conclude that the coating modulus, thickness and roughness are responsible for the mechanical improvement of fibres. Furthermore, we show that the hybrid coating layer is essential for enhanced interfacial adhesion strength of the glass fibre reinforced cement composites.