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Electrical Characteristics and Microstructures of Gd-Doped Bi4Ti3O12 Ceramics

Journal Key Engineering Materials (Volumes 336 - 338)
Volume High-Performance Ceramics IV
Edited by Wei Pan and Jianghong Gong
Pages 149-151
DOI 10.4028/www.scientific.net/KEM.336-338.149
Citation X.B. Liu et al., 2007, Key Engineering Materials, 336-338, 149
Online since April, 2007
Authors X.B. Liu, Y.H. Sun, Min Chen, Chong Qing Huang, J. Liu, Z.M. Wan
Keywords Bismuth Titanate, Electrical Properties, Impedance, Microstructure
Abstract

The electrical properties of Gd-doped bismuth titanates (Bi3.25Gd0.75Ti3O12, BGT) prepared by a conventional ceramic technique have been investigated. At applied d.c. field below 200V/mm, the current-voltage curve of the BGT ceramic exhibits a negative differential resistance behavior. The impedance spectrum indicates that the sample consists of semiconducting grain and moderately insulating grain boundary regions. XRD, SEM and EPMA analyses reveal crystalline phase characterized by a Bi-layered perovskite structure of Bi4Ti3O12 (BIT) and the distribution of every element is uniform. The BGT sample exhibits randomly oriented and plate-like morphology.

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