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Microwave Dielectric Properties of Ca[(Li1/3Nb2/3)0.95Zr0.15]O3+δ Ceramics with Ba2+ Substitution at A-Site

Journal Key Engineering Materials (Volumes 336 - 338)
Volume High-Performance Ceramics IV
Edited by Wei Pan and Jianghong Gong
Pages 196-198
DOI 10.4028/www.scientific.net/KEM.336-338.196
Citation Dong Xiang Zhou et al., 2007, Key Engineering Materials, 336-338, 196
Online since April, 2007
Authors Dong Xiang Zhou, G. Xiong, Shu Ping Gong, Jun Zhao, M.Z. Hu, H. Li
Keywords Microwave Dielectric Ceramics, Permittivity, Quality Factor, Temperature Coefficient of the Resonant Frequency
Abstract

The microwave properties of (Ca1-xBax)[(Li1/3Nb2/3)0.95Zr0.15]O3+δ(0.0≤x≤0.2, CBLNZ) ceramics were investigated. A single phase with orthorhombic perovskite structure was obtained at x = 0.0 − 0.025. Both the εr and Qf value firstly increased with increasing Ba2+ content, and then began to decrease at x = 0.025. The τf value increased from −9.4 ppm/ºC at x=0.0 to 18ppm/ºC at x=0.2, which could be explained by the decrease of B-site bond valence in perovskite structure.

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