Paper Title:
The Effect of Zn2+ Deficiency on Ordered Micro-Regions and Dielectric Properties of Pb(Zn1/3Nb2/3)O3-Based Relaxor Ceramics
  Abstract

0.85Pb(Zn1/3Nb2/3)O3-0.10BaTiO3-0.05PbTiO3 (abbreviated as PZN-based ceramics hereafter) ternary system ceramics with Zn2+ deficiency were synthesized by the columbite method. The effect of deficient Zn2+ on phase structure, ordered micro-region size and dielectric properties was investigated in detail. The analysis of Raman scattering spectra demonstrated that Zn2+ deficiency sharply enlarged the ordered micro-region size. Zn2+ deficiency significantly increased the dielectric constant, and decreased the diffusion degree of phase transition. There is a close correlation between effective ordered micro-regions size and dielectric properties for the PZN-based ceramics.

  Info
Periodical
Key Engineering Materials (Volumes 336-338)
Edited by
Wei Pan and Jianghong Gong
Pages
27-29
DOI
10.4028/www.scientific.net/KEM.336-338.27
Citation
S. B. Qu, B. K. Wang, Z. Y. Liu, Z. B. Pei, Z. Xu, "The Effect of Zn2+ Deficiency on Ordered Micro-Regions and Dielectric Properties of Pb(Zn1/3Nb2/3)O3-Based Relaxor Ceramics", Key Engineering Materials, Vols. 336-338, pp. 27-29, 2007
Online since
April 2007
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