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Fabrication and Fuel-Cell Properties of Sm-Doped CeO2 Electrolyte Film by Electrophoretic Deposition

Journal Key Engineering Materials (Volume 350)
Volume Electroceramics in Japan X
Edited by K. Katayama, K. Kato, T. Takenaka, M. Takata and K. Shinozaki
Pages 175-178
DOI 10.4028/www.scientific.net/KEM.350.175
Citation Satoshi Nakayama et al., 2007, Key Engineering Materials, 350, 175
Online since October, 2007
Authors Satoshi Nakayama, Masaru Miyayama
Keywords Electrophoretic Deposition (EPD), Film, Samarium-Doped Ceria, Solid Oxide Fuel Cell (SOFC)
Abstract

Electrolyte films of Ce0.8Sm0.2O1.9 (SDC) were prepared on NiO-SDC anode substrates by electrophoretic deposition (EPD) for intermediate-temperature solid oxide fuel cells (SOFCs). Dense and crack-free films were fabricated by cofiring the films and substrates. A cell using an SDC electrolyte film with a La0.6Sr0.4CoO3-δ cathode exhibited a power density of 281 mW/cm2 and an electrolyte resistance of 0.064 cm2 at 600ºC. The film formation of SDC by EPD was found effective in decreasing the electrolyte resistance.

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