Ceramic is difficult to cut with normal machining method in precision intricate profile. The grinding process with diamond abrasive wheel is an effective process to machining ceramic materials. In this paper, a precise form-grinding method of ceramic materials with diamond grinding wheel is introduced. The tolerance of intricate profiler precision degree by this grinding process is less than 0.005mm. The machining process contains many techniques as high efficiency of profiler dressing technique of diamond wheel and form grinding process of ceramic. It gives some references on the developing of ceramic precision intricate profile machining techniques forward.