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A Novel SiC Precursor with High Ceramic Yield: Antimony-Substituted Polysilane (APS)

Journal Key Engineering Materials (Volumes 368 - 372)
Volume High-Performance Ceramics V
Edited by Wei Pan and Jianghong Gong
Pages 818-820
DOI 10.4028/www.scientific.net/KEM.368-372.818
Citation Lin Liu et al., 2008, Key Engineering Materials, 368-372, 818
Online since February, 2008
Authors Lin Liu, Xin Xing, Xiao Dong Li
Keywords Ceramic Precursor, PMS, Silicon Carbide (SiC)
Abstract

A novel SiC precursor antimony-substituted polymethylsilane (APS) is present in this paper. First, pre-APS was synthesized from polymethylsilane (PMS) and SbCl3 at room temperature. Pre-APS was a liquid mixture and could be used in PIP process without solvent. After the elemination of HCl and the crosslinking of pre-APS, the novel precursor APS with the ceramic yield 91% was prepared.

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