Paper Title:
Sol-Gel Synthesis of FHA Nanoparticles and CDHA Agglomerates from a Mixture with a Nonstochiometric Ca/P Ratio
  Abstract

The aim of this study was to investigate the sol gel synthesis of HA/FA nanoparticles and the possible formation of TCP phase or unstoichiometric calcium deficient hydroxyapatite (CDHA) from the precursors with a Ca/P ratio of 1.62. In order to prepare the sol, the solutions of Triethyl phosphite, ammonium fluoride and calcium nitrate in ethanol were used respectively as P, F and Ca precursors. The crystallinity, particle and crystallite size, powder morphology, chemical structure and phase analysis were investigated by SEM, XRD, FT-IR and Zeta sizer experiment. A multiphase compound containing hydroxyapatite (HA) and fluoroapatite (FA) nanoparticles and calcium deficient hudroxyapatite (CDHA) agglomerates was obtained. The size of the crystallites estimated from XRD patterns using Scherrer equation and the crystallinity of HA phase were about 5 nm and 66% respectively. The zeta sizer experiments for the dispersed particles in its own conditions showed an average size of 98 nm.

  Info
Periodical
Key Engineering Materials (Volumes 396-398)
Main Theme
Edited by
Marcelo Prado and Cecília Zavaglia
Pages
607-610
DOI
10.4028/www.scientific.net/KEM.396-398.607
Citation
R. Jahandideh, A. Behnamghader, M. Rangie, A. Youzbashi, S. Joughehdoust, R. Tolouei, "Sol-Gel Synthesis of FHA Nanoparticles and CDHA Agglomerates from a Mixture with a Nonstochiometric Ca/P Ratio", Key Engineering Materials, Vols. 396-398, pp. 607-610, 2009
Online since
October 2008
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$32.00
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