Paper Title:
Solvent-Free Synthesis of Siloxanes and their Usage as Potential Cross-Coupling Reagents
  Abstract

Hexaarylcyclotrisiloxanes were selectively prepared by solvent-free synthesis from diarylsilanediol. These well-known stable compounds were found to undergo palladium-catalyzed cross-coupling reaction with aryl halides in good yields. All of attached aryl groups on silicon atom could be utilized. Furthermore, base-sensitive functionality such as acetyl and nitro groups survived the reaction.

  Info
Periodical
Edited by
Osamu Hanaizumi and Masafumi Unno
Pages
43-47
DOI
10.4028/www.scientific.net/KEM.459.43
Citation
M. Unno, R. Tanaka, D. Obinata, M. Endo, T. Sakurai, S. Ojima, T. Katayama, K. Fugami, "Solvent-Free Synthesis of Siloxanes and their Usage as Potential Cross-Coupling Reagents", Key Engineering Materials, Vol. 459, pp. 43-47, 2011
Online since
December 2010
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