Paper Title:
Synthesis and Structural Consideration of Metal-Organic Framework (MOF) Coordination Polymer with Various Metal Linker Ratios
  Abstract

Metal-organic framework MOF-5 (i.e. IRMOF-1) with the chemical structure of Zn4O(BDC)3 were successfully synthesized using room temperature synthesis approach of direct-mixing method ans liquid-crystal templating method. The metal clusters organic linker used was benzenedicarboxylic acid (BDC). Direct-mixing approach resulted in MOF-5 with tetragonal cell while the liquid-crystal templating method resulted in cubic structure. The metal/linker ratios were varied from 0.1 to 1 to study the effect of metal linker on the formation of MOF-5 materials and their characteristics. The crystallinity of the evacuated framework MOF-5 materials were increased when the metal/organic linker ratios were increased from 0.3 to 0.5. However, the cubic structure of the evacuated framework was relatively disrupted at metal/linker ratio 0.7.

  Info
Periodical
Key Engineering Materials (Volumes 462-463)
Edited by
Ahmad Kamal Ariffin, Shahrum Abdullah, Aidy Ali, Andanastuti Muchtar, Mariyam Jameelah Ghazali and Zainuddin Sajuri
Pages
1103-1108
DOI
10.4028/www.scientific.net/KEM.462-463.1103
Citation
H. Misran, A. M. Adminuddin, F. A. M. Zini, R. Singh, "Synthesis and Structural Consideration of Metal-Organic Framework (MOF) Coordination Polymer with Various Metal Linker Ratios", Key Engineering Materials, Vols. 462-463, pp. 1103-1108, 2011
Online since
January 2011
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$32.00
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