Paper Title:
Spectral and Thermal Investigation of Novel Glycine-Based Schiff Base Derivative and its Metal Complexes
  Abstract

A novel glycine-based Schiff base derivative (abbreviated as C16GlySb) containing long alkyl chain was synthesized from glycine reacted with 4-cetyloxy-2-hydroxybenzaldehyde and sequentially coordinated with various metal ions to give the corresponding metal complexes (abbreviated as G-M). The products were characterized by UV-Vis spectra and FT-IR spectra. At the same time, the thermal stability was measured by TG-DTA instrument. FT-IR analysis indicated that the nitrogen atom in imino group, oxygen atom in phenolic hydroxyl group, and carboxylic ion participated in coordinating with transition metal ion in doubly-bridged mode. UV spectra showed that compared with ethanol solution, the cast film on quartz plate showed H-type or J-type aggregate structure. In addition, the thermal stability of G-M had been obviously superior to that of the ligand C16GlySb. The present results have showed potential application in fields of functional material and catalyst.

  Info
Periodical
Key Engineering Materials (Volumes 474-476)
Edited by
Garry Zhu
Pages
543-547
DOI
10.4028/www.scientific.net/KEM.474-476.543
Citation
T. F. Jiao, J. Zhou, J. X. Zhou, Y. Y. Xing, X. H. Li, "Spectral and Thermal Investigation of Novel Glycine-Based Schiff Base Derivative and its Metal Complexes", Key Engineering Materials, Vols. 474-476, pp. 543-547, Apr. 2011
Online since
April 2011
Price
US$ 28,-
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