The integration of network education technology and mathematics curriculum has become the hot issue of mathematics teaching reform in higher vocational education institutions. The paper has emphatically introduced the construction situation and implementation process of network education in advanced mathematics. Through investigation and statistical analysis on network education teaching effect, it verified that network education has the superiority that the conventional education cannot match. However, each teaching model has its own advantages and disadvantages. Finally, based on the teaching practice, the paper made some suggestions and countermeasures on further development of network education, and provided the valuable teaching experimental basis for the mathematics educators.