Paper Title:
The Structure Investigation of Copper, Nickel and Iron Hexacyanometalates from Conventional X-Ray Powder Diffraction Data
  Abstract

The crystal structure of new Prussian blue analogue samples, KCu[Fe1-x Cox(CN)6], KNi[Fe1-x Cox(CN)6] and Fe[Fe1-x Cox(CN)6], was solved on the base of the model from Keggin and Miles [1] and refined by the Rietveld method [2] from conventional X-ray powder diffraction data. These compounds form mixed crystals for all Fe/Co ratios. The crystal structure of the KCu[Fe0.3Co0.7(CN)6], KNi[Fe0.3Co0.7(CN)6] and Fe[Fe0.8Co0.2(CN)6] is presented in detail. For both potassium containing compounds the disorder in the potassium arrangement is the most obvious characteristic.

  Info
Periodical
Materials Science Forum (Volumes 443-444)
Edited by
Yvonne Andersson, Eric J. Mittemeijer and Udo Welzel
Pages
345-348
DOI
10.4028/www.scientific.net/MSF.443-444.345
Citation
I. Petrovic-Prelevic, A. Widmann, H. Kahlert, H. Wulff, F. Scholz, "The Structure Investigation of Copper, Nickel and Iron Hexacyanometalates from Conventional X-Ray Powder Diffraction Data", Materials Science Forum, Vols. 443-444, pp. 345-348, 2004
Online since
January 2004
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