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Composition Dependent Fatigue in Antiferroelectric PZST Ceramics Induced by Bipolar Electric Cycling

Journal Materials Science Forum (Volumes 475 - 479)
Volume PRICM-5
Edited by Z.Y. Zhong, H. Saka, T.H. Kim, E.A. Holm, Y.F. Han and X.S. Xie
Pages 1193-1196
DOI 10.4028/www.scientific.net/MSF.475-479.1193
Citation Long Jie Zhou et al., 2005, Materials Science Forum, 475-479, 1193
Online since January, 2005
Authors Long Jie Zhou, Georg Rixecker, André Zimmermann, Fritz Aldinger
Keywords Antiferroelectric, Composition, Fatigue, Microstructure, Strain Hysteresis Loop
Abstract

Bipolar electric fatigue in antiferroelectrics of the lead zirconate titanate stannate ceramics family was investigated. Variations in strain hysteresis loops and damages in microstructure of the materials due to the electric cycling were analyzed. The materials showed symmetric or asymmetric suppression of strain hysteresis loop, normal or diffuse AFE-FE phase transition and intact or damaged microstructure after 5×10-7 cycles, indicating a strong composition dependent fatigue effect and the corresponding mechanism. In general, the antiferroelectric materials exhibited much higher fatigue resistance than ferroelectric ceramics reported previously.

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