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Surface Morphology Evolution during LP-MOCVD Growth of ZnO on Sapphire

Journal Materials Science Forum (Volumes 475 - 479)
Volume PRICM-5
Edited by Z.Y. Zhong, H. Saka, T.H. Kim, E.A. Holm, Y.F. Han and X.S. Xie
Pages 1693-1696
DOI 10.4028/www.scientific.net/MSF.475-479.1693
Citation Jian Dong Ye et al., 2005, Materials Science Forum, 475-479, 1693
Online since January, 2005
Authors Jian Dong Ye, Shu Lin Gu, Su Min Zhu, S.M. Liu, Feng Qin, W. Liu, X. Zhou, R. Zhang, Y. Shi, Y.D. Zheng
Keywords Atomic Force Microscope (AFM), Buffer, Morphology, Zinc Oxide ZnO
Abstract

The morphology evolution of ZnO films grown on sapphire (0001) by MOCVD have been studied as a function of buffer growth time and temperature by means of atomic-force microscope (AFM), x-ray diffractions (XRD) and optical microscopy. When the buffer growth temperature decreased to 450℃, the surface became smooth greatly, indicating the transition from typical 3D island growth to quasi-2D growth mode. As the buffer growth time exceeds 5min, the micron-sized pit-like features are formed. It is due to the lack of stabilization of adatoms under the “etching” action of ionized O2/Ar during high temperature buffer annealing

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