Paper Title:
Metal-Complex Hydrides for Hydrogen-Storage Application
  Abstract

Metal-complex hydrides Li3AlH6 and V-doped Li3AlH6 nanoparticles were synthesized by solid reactions of LiH and LiAlH4 in the absence and in the presence of VCl3, respectively. X-ray diffraction, transmission electron microscopy, X-ray photoelectron spectroscopy, Brunauer- Emmett-Teller sorption, thermogravimetry and differential thermal analysis have been used to investigate the phase composition, microstructure and surface properties. Not only the nanocrystalline Li3AlH6, but also the coexisting catalyst with “valence-transfer” state can influence the dehydrogenation kinetics. The extension of the catalytic mechanism is attractive for reversible hydrogen storage of the alanate system.

  Info
Periodical
Materials Science Forum (Volumes 475-479)
Main Theme
Edited by
Z.Y. Zhong, H. Saka, T.H. Kim, E.A. Holm, Y.F. Han and X.S. Xie
Pages
2437-2440
DOI
10.4028/www.scientific.net/MSF.475-479.2437
Citation
X. L. Gou, L. N. Xu, W. Y. Li, J. Chen, Q. Xu, "Metal-Complex Hydrides for Hydrogen-Storage Application", Materials Science Forum, Vols. 475-479, pp. 2437-2440, 2005
Online since
January 2005
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Price
$32.00
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