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Corrosion of Ni-W Coatings in SO2 Atmosphere between 500 and 700 °C

Journal Materials Science Forum (Volumes 486 - 487)
Volume Eco-Materials Processing & Design VI
Edited by Hyung Sun Kim, Sang-Yeop Park, Bo Young Hur and Soo Wohn Lee
Pages 169-172
DOI 10.4028/www.scientific.net/MSF.486-487.169
Citation Dong Bok Lee et al., 2005, Materials Science Forum, 486-487, 169
Online since June, 2005
Authors Dong Bok Lee, J.H. Ko
Keywords Coating, Corrosion, Nickel-Tungsten, Oxidation, Sulfidation
Abstract

The Ni-19at.%W coating was electodeposited to protect the stainless steel substrate, and then corroded between 500 and 700oC in Ar-0.2% SO2 atmosphere for 5 hr. The coating effectively protected the substrate from corrosion at 500oC, but failed at 700oC owing to serious corrosion. The corrosion products were mainly NiO, WO3 and NiWO4, together with some NiS, FeS, Fe2O3 and FeWO4. Detailed scale morphologies and corrosion mechanism are presented.

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