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Metastable Phase Formation in Undercooled Nd-Fe-B Alloys Investigated by In Situ Diffraction Using Synchrotron Radiation

Journal Materials Science Forum (Volume 508)
Volume Solidification and Gravity IV
Edited by A Roósz, M. Rettenmayr and Z. Gácsi
Pages 81-86
DOI 10.4028/www.scientific.net/MSF.508.81
Citation Joern Strohmenger et al., 2006, Materials Science Forum, 508, 81
Online since March, 2006
Authors Joern Strohmenger, J.R. Gao, Thomas Volkmann, Dieter M. Herlach
Keywords Electromagnetic Levitation, Metastable Phase, Nd-Fe-B, Solidification, Synchrotron Radiation (XRD), Undercooling
Abstract

Diffraction experiments on electromagnetically levitated Nd-Fe-B alloys during solidification of the undercooled melt have been performed at the European Synchrotron Radiation Facility (ESRF). By using high intensity synchrotron radiation complete diffraction spectra could be detected within a short period of some seconds thus enabling the observation of metastable solidification products that exhibits a limited lifetime. A metastable phase that crystallizes in wide composition range and that initiates the solidification of the stable Nd2Fe14B1-phase (φ-phase) have been observed.

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