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Desorption Behaviour in Nanostructured MgH2-Co

Journal Materials Science Forum (Volume 518)
Volume Recent Developments in Advanced Materials and Processes
Edited by Dragan P. Uskokovic, Slobodan K. Milonjic and Dejan I. Rakovic
Pages 79-84
DOI 10.4028/www.scientific.net/MSF.518.79
Citation Amelia Montone et al., 2006, Materials Science Forum, 518, 79
Online since July, 2006
Authors Amelia Montone, Jasna Grbović Novaković, Lj. Stamenković, Anna Lisa Fiorini, Luca Pasquini, Ennio Bonetti, Marco Vittori Antisari
Keywords Hydrogen Storage, Magnesium Hydride, Mechanical Milling, Microstructure, Scanning Electron Microscope (SEM)
Abstract

The influence of the Co addition and synthesis route on desorption properties of MgH2 were investigated. Ball milling of MgH2-Co blends was performed under Ar using different milling intensities and different weight ratios. Microstructural and morphological characterization, performed by XRD and SEM, show a huge correlation with thermal stability and hydrogen desorption properties investigated by DSC. A complex desorption behaviour is correlated with the dispersion of the catalytic particles that appears to play a main role in desorption performances. The optimum catalyst concentration was found to be around 10 wt.%, while the optimum value of the ball to powder ratio was 10:1.

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