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Hydrogen Effect on SiC Single Crystal Prepared by the Physical Vapor Transport Method

Journal Materials Science Forum (Volumes 556 - 557)
Volume Silicon Carbide and Related Materials 2006
Edited by N. Wright, C.M. Johnson, K. Vassilevski, I. Nikitina and A. Horsfall
Pages 25-28
DOI 10.4028/www.scientific.net/MSF.556-557.25
Citation Jung Gon Kim et al., 2007, Materials Science Forum, 556-557, 25
Online since September, 2007
Authors Jung Gon Kim, Joon Ho An, Jung Doo Seo, Jung Kyu Kim, Myung Ok Kyun, Won Jae Lee, Il Soo Kim, Byoung Chul Shin, Kap Ryeol Ku
Keywords Crystal Boules, Crystal Quality, Hydrogen, PVT, Sublimation
Abstract

We investigated the effects of hydrogen addition to the growth process of SiC single crystal using sublimation physical vapor transport (PVT) techniques. Hydrogen was periodically added to an inert gas for the growth ambient during the SiC bulk growth. Grown 2”-SiC single crystals were proven to be the polytype of 6H-SiC and carrier concentration levels of about 1017/cm3 was determined from Hall measurements. As compared to the characteristics of SiC crystal grown without using hydrogen addition, the SiC crystal grown with periodically modulated hydrogen addition definitely exhibited lower carrier concentration and lower micropipe density as well as reduced growth rate.

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