Paper Title:
Grain-Boundary Structure and Phase-Transformation Mechanism in Yttria-Stabilized Tetragonal Zirconia Polycrystal
  Abstract

The microstructures in 3 mol% Y2O3-stabilized tetragonal zirconia polycrystal (Y-TZP) sintered at 1100°-1650°C were investigated to clarify cubic-formation and grain-growth mechanisms. The cubic phase in Y-TZP appeared at 1300°C and its mass fraction increased with increasing sintering temperature. High-resolution transmission electron microscopy (HRTEM) and nanoprobe X-ray energy dispersive spectroscopy (EDS) measurements revealed that no amorphous layer existed along the grain-boundary faces in Y-TZP, and Y3+ ions segregated not only along the tetragonal-tetragonal phase boundaries but also along tetragonal-cubic phase boundaries. Scanning transmission electron microscopy (STEM) and nanoprobe EDS measurements revealed that the Y3+ ion distribution was nearly homogeneous up to 1300°C, but cubic phase regions with high Y3+ ion concentration clearly formed inside grains at 1500°C. These results indicate that cubic phase regions are formed from the grain boundaries and/or the multiple junctions in which Y3+ ions segregated. We termed such a new diffusive transformation phenomenon “grain boundary segregation-induced phase transformation (GBSIPT)”. The grain-growth mechanism is controlled by the solute-drag effect of Y3+ ions segregating along the grain boundary.

  Info
Periodical
Materials Science Forum (Volumes 558-559)
Edited by
S.-J.L. Kang, M.Y. Huh, N.M. Hwang, H. Homma, K. Ushioda and Y. Ikuhara
Pages
921-926
DOI
10.4028/www.scientific.net/MSF.558-559.921
Citation
K. Matsui, H. Yoshida, Y. Ikuhara, "Grain-Boundary Structure and Phase-Transformation Mechanism in Yttria-Stabilized Tetragonal Zirconia Polycrystal", Materials Science Forum, Vols. 558-559, pp. 921-926, 2007
Online since
October 2007
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$32.00
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