Paper Title:

Atomic-Scale Processes of Grain-Boundary Faceting in a Zirconia Bicrystal

Periodical Materials Science Forum (Volumes 558 - 559)
Main Theme Recrystallization and Grain Growth III
Edited by S.-J.L. Kang, M.Y. Huh, N.M. Hwang, H. Homma, K. Ushioda and Y. Ikuhara
Pages 955-958
DOI 10.4028/www.scientific.net/MSF.558-559.955
Citation Naoya Shibata et al., 2007, Materials Science Forum, 558-559, 955
Online since October, 2007
Authors Naoya Shibata, Fumiyasu Oba, Takahisa Yamamoto, Yuichi Ikuhara
Keywords Bicrystal, Faceting, Grain Boundary Atomic Structure, High Resolution Electron Microscopy (HREM), Static Lattice Calculations, Zirconia
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Abstract

In this paper, we characterized atomic structure of a Σ = 3, [110]/{112} grain boundary in a yttria-stabilized cubic zirconia bicrystal. High-resolution transmission electron microscopy (HRTEM) clearly revealed that the grain boundary migrated to form {111}/{115} periodical facets, although the bicrystal was initially joined so as to have the symmetric straight boundary plane of {112}. Atomic-scale process for the facet growth could be modeled by the continuous flippings of atoms at the boundary core.